Strategies for Improving the Tribological Characteristics of TiN/а-C Coatings
https://doi.org/10.32864/0202-4977-2025-46-5-415-424
Abstract
This work investigates the mechanical properties and tribological characteristics of TiN (single layer) and TiN/a-C (double layer, two types of combinations of elastic-plastic properties of media) coatings based on experimental and theoretical approaches. The microstructure of the synthesized coatings and the relief of the front surface were examined using a scanning electron microscope. The analysis of the conformity of the a-C coating was performed using the disturbed total internal reflection method with an IR Fourier spectrometer. The hardness and reduced elastic modulus of the samples were determined through continuous indentation using a Berkovich pyramid. The intensity of wear and the friction coefficient were determined in a sliding friction mode. The findings of a thorough experimental investigation into the coatings were instrumental in formulating a finite element model of indentation into a two-layer elastic-plastic medium, incorporating varied combinations of elastic and plastic characteristics, as well as distinct relative layer thicknesses. The correlation between the parameters of the considered coatings H/E and H3/E2 and the wear intensity was established through experimental means. Theoretically, the functional dependencies of hardness and reduced elastic modulus on the relative thickness of the face metastable layer a-C were established. The optimal thickness ratio of the TiN/a-C coating layers has been determined for given elastic-plastic characteristics of the materials. Such a coating will exhibit optimal tribological characteristics.
About the Authors
O. A. BelyakRussian Federation
Rostovskogo Strelkovogo Polka Narodnogo Opolcheniya Sq., 2, Rostov-on-Don 344038
Chekhov Ave., 41, Rostov-on-Don 344006
V. I. Kolesnikov
Russian Federation
Rostovskogo Strelkovogo Polka Narodnogo Opolcheniya Sq., 2, Rostov-on-Don 344038
D. V. Maksimov
Russian Federation
Rostovskogo Strelkovogo Polka Narodnogo Opolcheniya Sq., 2, Rostov-on-Don 344038
E. D. Anikina
Russian Federation
Rostovskogo Strelkovogo Polka Narodnogo Opolcheniya Sq., 2, Rostov-on-Don 344038
Chekhov Ave., 41, Rostov-on-Don 344006
M. M. Chetverik
Russian Federation
Rostovskogo Strelkovogo Polka Narodnogo Opolcheniya Sq., 2, Rostov-on-Don 344038
References
1. Aghaei A.A., Eshaghi A., and Karami E. Silicon Solar Cell Performance Deposited by Diamond Like Carbon Thin Film “Atomic Oxygen Effects” // Acta Astronautica. — 2017 (138), 369—373
2. Pavlenko V.I., Cherkashina N.I., and Zaitsev S.V. Fabrication and Characterization of Nanocomposite Films Al, Cu/Al and Cr/Al Formed on Polyimide Substrate // Acta Astronautica. — 2019 (160), 489—498
3. Santos M.D., Fukumasu N.K., Tschiptschin A.P., Lima N.B., Figueroa C.A., Weber J.S., Souza R.M., and Machado I.F. Effect of Ti/Si and Ti/TiN/Si Interlayers on the Structure, Properties, and Tribological Behavior of an a-C Film Deposited onto a C17200 Copper-Beryllium Alloy // Surface and Coatings Technology. — 2022 (441), 128561
4. Liu L., Wu Z., An X., Xiao S., Cui S., Lin H., Fu R.K.Y., Tian X., Wei R., Chu P.K., and Pan F. Excellent Adhered Thick Diamond-Like Carbon Coatings by Optimizing Hetero-Interfaces with Sequential Highly Energetic Cr and C Ion Treatment // Journal of Alloys and Compounds. — 2018 (735), 155—162
5. Song Z., Liu Y., Liu Yu., Jiang X., Pilipstou D.G., and Rogachev A.V. Improving the Protective Properties of an Artificial Joint Friction Couple by Using TiN and DLC Films // Surface and Coatings Technology. — 2023 (472), 129944
6. Chen X., Du Y., and Chung Y.-W. Commentary on Using H/E and H3/E2 as Proxies for Fracture Toughness of Hard Coatings // Thin Solid Films. — 2019 (688), 137265
7. Lepicka M., Grądzka-Dahlke M., Pieniak D., Pasierbiewicz K., and Niewczas A. Tribological Performance of Titanium Nitride Coatings: A Comparative Study on TiN-Coated Stainless Steel and Titanium Alloy // Wear. — 2019 (422-423), 68—80
8. Belyak O.A., Suvorova T.V., and Manturov D.S. Study of Tribological and Mechanical Characteristics of Wear-Resistant Coatings Taking into Account Their Elastoplastic Properties // Journal of Friction and Wear. — 2025 (45), no. 5, 280—286
9. Kolesnikov V.I., Kudryakov O.V., Voropaev A.I., Kolesnikov I.V., Varavka V.N., Lifar M.S., Guda A.A., Manturov D.S., and Novikov E.S. Formation and Prediction of the Properties of Ion-Plasma Diamond-Like Coatings under Nitrogen Stabilization // Journal of Friction and Wear. — 2024 (45), no. 1, 9—17
10. Pashkov D.M., Belyak O.A., Guda A.A., and Kolesnikov V.I. Reverse Engineering of Mechanical and Tribological Properties of Coatings: Results of Machine Learning Algorithms // Physical Mesomechanics. — 2022, no. 4 (25), 296—305
11. McMaster S.J., Kosarieh S., Liskiewicz T.W., Neville A., and Beake B.D. Utilising H/E to Predict Fretting Wear Performance of DLC Coating Systems // Tribology International. — 2023 (185), 108524
12. Robertson J. Diamond-Like Amorphous Carbon // Materials Science and Engineering: R: Reports. — 2002 (37), 129—281
13. Konshina E.A. and Vangonen A.I. Features of the Vibrational Spectra of Diamond-Like and Polymer-Like a-C:H Films // Semiconductors. — 2005 (39), 585—590
14. Vatulyan A.O. and Belyak O.A. An Asymptotic Approach to the Calculation of Wave Fields in a Layer with a Defect with a Small Characteristic Size // Acoustical Physics. — 2020 (66), 213—219
15. Belyak O.A., Suvorova T.V. The effect of the microstructure of the base on the friction forces during the movement of a flat punch // Ekologicheskiy Vestnik Nauchnykh Tsentrov Chernomorskogo Ekonomicheskogo Sotrudnichestva. — 2018, № 3(15), 25—31 (in Russian)
Review
For citations:
Belyak O.A., Kolesnikov V.I., Maksimov D.V., Anikina E.D., Chetverik M.M. Strategies for Improving the Tribological Characteristics of TiN/а-C Coatings. Title in english. 2025;46(5):415-424. (In Russ.) https://doi.org/10.32864/0202-4977-2025-46-5-415-424
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